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portada Applications of Supercritical Fluids in Industrial Analysis
Type
Physical Book
Author
Publisher
Language
English
Pages
224
Format
Paperback
Dimensions
23.4 x 15.6 x 1.3 cm
Weight
0.35 kg.
ISBN13
9789401049511
Categories

Applications of Supercritical Fluids in Industrial Analysis

J. R. Dean (Author) · Springer · Paperback

Applications of Supercritical Fluids in Industrial Analysis - Dean, J. R.

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Synopsis "Applications of Supercritical Fluids in Industrial Analysis"

The continued search for rapid, efficient and cost-effective means of analytical measurement has introduced supercritical fluids into the field of analytical chemistry. Two areas are common: supercritical fluid chroma- tography and supercritical fluid extraction. Both seek to exploit the unique properties of a gas at temperatures and pressures above the critical point. The most common supercritical fluid is carbon dioxide, employed because of its low critical temperature (31 C), inertness, purity, non-toxicity and cheapness. Alternative supercritical fluids are also used and often in conjunction with modifiers. The combined gas-like mass transfer and liquid-like solvating characteristics have been used for improved chroma- tographic separation and faster sample preparation. Supercritical fluid chromatography (SFC) is complementary to gas chro- matography ( GC) and high performance liquid chromatography (HPLC), providing higher efficiency than HPLC, together with the ability to analyse thermally labile and high molecular weight analytes. Both packed and open tubular columns can be employed, providing the capability to analyse a wide range of sample types. In addition, flame ionization detection can be used, thus providing 'universal' detection.

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